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Fucose (1MEOX) (4TMS) MP


Replica Mass Spectra of Fucose (1MEOX) (4TMS) MP

replicalib entry datedetectionmethodspecies
112 May 2005  M[NIST] 
2328 August 2012  MassBank GC 2010 Tsujimoto 
2103 November 2010  Schomburg_GC_2010 
201 October 2001 MS-TOFM[EIGTMS]Saccharomyces cerevisiae
419 January 2005 MS-QUADM[ROE] 
601 May 2001 MS-TOFM[EIGTMS]Standard Addition
711 September 2005  M[FAME4090]Standard
826 November 2004  M[FAME4090]Standard
922 February 2005 MS-TOFM[STR] 
1001 July 2001 MS-QuadM[2]Standard
21 spectrum(a)
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Spectrum Details

analyteFucose (1MEOX) (4TMS) MP
analyte InChIInChI=1S/C19H47NO5Si4/c1-16(22-26(3,4)5)18(24-28(9,10)11)19(25-29(12,13)14)17(15-20-21-2)23-27(6,7)8/h15-19H,1-14H3/b20-15+/t16-,17+,18+,19-/m1/s1
analyte mass481.92
authorsLiebig F, Erban A, Max Planck Institute of Molecular Plant Physiology, Department of Molecular Plant Physiology (Prof. Willmitzer L), Am Muehlenberg 1, D-14476 Golm, Germany
lib entry date01 February 2005
metabolite roleMETB
retention time (sec)1,068.56
retention index (VAR5 method, n-alkanes C10–C36)1,719.6 (predicted, according to Strehmel, N. et.al)
base peak (m/z)117
maximal intensity999
mass-intensity-peaks cardinality199 intensities
minimal m/z70
maximal m/z481
download JCAMP DXSpectrumJcampDx.ashx?id=63556480-1647-46b2-ade6-47cc8589db40
download MSPSpectrumMsp.ashx?id=63556480-1647-46b2-ade6-47cc8589db40


citationErban A, Schauer N, Fernie AR, Kopka J (2006) In: Weckwerth W (ed): Methods in Molecular Biology Vol., Humana Press Inc., Totowa, USA
deconvolutionChromaTOF V1.00 (Pegasus Driver 1.61), LECO, St. Joseph, MI, USAOFFSET:1_SMOOTHING:3_WIDTH:6_SN:>2
derivatizationMEOX; TMSMethoxyamination:90min40°C; Trimethylsilylation:45min40°C
detectorMS-TOFMZ:70-600; SCANS:20/s; Pegasus III TOF-MS; LECO, St. Joseph, MI, USA
extractionmethanol:water (4:1; v/v); 15min70°C 
ion sourceEI70eV
metabolic inactivationcut; liquid nitrogen; -80°C 
partitioningmethanol fraction of a methanol:water:chloroform (approx. 2:2:1, v/v/v) partitioning 
RIALKANEC12, C15, C18, C19, C22, C28, C32, C36
separationGCCOLUMN:5%diphenyl-95%dimethylpolysiloxane (arylene), 30+10m, ID:0.25mm, DF:0.25microm, Rtx-5SilMS Integra-Guard, #525560 (Restek, Bad Homburg, Germany); PROGRAM:iso1min70°C, ramp9°C/min, iso5min350°C; FLOW:Helium, 0.6ml/min; INJECTION:1microL, splitless, 230°C; TRANSFER:250°C; IONSOURCE:250°C

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