GOLM METABOLOME DATABASE
How would you rate the quality of this mass spectrum?
poor, not helpful 
 outstanding, most helpful.
This spectrum was 0 times rated; on average=0.0

Glucose-6-phosphate (1MEOX) (6TMS) MP

 

Replica Mass Spectra of Glucose-6-phosphate (1MEOX) (6TMS) MP

replicalib entry datedetectionmethodspecies
112 June 2003 MS-QuadM[2]Arabidopsis thaliana
301 December 2003 MS-QuadM[2]Standard
412 May 2005  M[NIST] 
2705 June 2013  MRI_2013 
522 February 2005 MS-TOFM[STR] 
619 July 2007 MS-TOFVAR5Reference Substance
815 March 2005 MS-TOFM[6]Reference Substance
2430 March 2011  Fiehn_GC_2010 
1001 January 2002 MS-TOFM[EIGTMS]Standard
2628 August 2012  MassBank GC 2010 Ara 
24 spectrum(a)
rotate: click+drag; translate: alt+click+drag; zoom: mousewheel; save: mol

Spectrum Details

analyteGlucose-6-phosphate (1MEOX) (6TMS) MP
analyte InChIInChI=1S/C25H64NO9PSi6/c1-28-26-20-22(30-37(2,3)4)24(32-39(8,9)10)25(33-40(11,12)13)23(31-38(5,6)7)21-29-36(27,34-41(14,15)16)35-42(17,18)19/h20,22-25H,21H2,1-19H3/b26-20+/t22-,23+,24+,25+/m0/s1
analyte mass722.26
chromatogram1313EC75
citationWagner C, Sefkow M, Kopka J (2003) Phytochemistry 62, 887-900
authorsKopka J, Max Planck Institute of Molecular Plant Physiology, Department of Molecular Plant Physiology (Prof. Willmitzer L), Am Muehlenberg 1, D-14476 Golm, Germany
lib entry date01 October 2001
metabolite roleMETB-METB
retention time (sec)866.4
retention index (VAR5 method, n-alkanes C10–C36)2.308,72 (predicted, according to Strehmel, N. et.al)
base peak (m/z)73
maximal intensity999
mass-intensity-peaks cardinality123 intensities
minimal m/z70
maximal m/z473
download JCAMP DXSpectrumJcampDx.ashx?id=28877cb9-225b-4f07-b9af-5738c698d38b
download MSPSpectrumMsp.ashx?id=28877cb9-225b-4f07-b9af-5738c698d38b

GC-Method

nameM[EIGTMS]
citationWagner C, Sefkow M, Kopka J (2003) Phytochemistry 62, 887-900
attributetextdetails
deconvolutionAMDIS, National Institute of Standards and Technology, Gaithersburg, MD, USADIRECTION:non scanning; WIDTH: 20; SUBTRACTION: two; RESOLUTION: high; SENSITIVITY: medium; SHAPE: high
derivatizationMEOX; TMSMethoxyamination:60min37°C; Trimethylsilylation:>60min37°C
detectorMS-TOFMZ:70-600; SCANS:6/s; Pegasus II TOF-MS; LECO, St. Joseph, MI, USA
extractionmethanol:water (4:1; v/v); 15min70°C 
ion sourceEI70eV
metabolic inactivationcut; liquid nitrogen; -80°C 
partitioningmethanol fraction of a methanol:water:chloroform (approx. 2:2:1, v/v/v) partitioning 
RIALKANEC12, C15, C19, C22, C28, C32, C36
separationGCCOLUMN:5%diphenyl-95%dimethylpolysiloxane (arylene), 30+10m, ID:0.25mm, DF:0.25microm, Rtx-5SilMS Integra-Guard, #NA (Restek, Bad Homburg, Germany); PROGRAM:iso2min80°C, ramp15°C/min, iso2min350°C; FLOW:Helium, 1.0ml/min; INJECTION:1microL, splitless, 230°C, 2min110psi; TRANSFER:250°C; IONSOURCE:200°C

comments on this mass spectrum

Post a Comment
Name:
 
Website:  
Email:
Comments:
service last updated 17/02/2017 © 2008-2014 Golm Metabolome Database - All rights reserved
Top