How would you rate the quality of this mass spectrum?
poor, not helpful 
 outstanding, most helpful.
This spectrum was 0 times rated; on average=0.0

Glucose-6-phosphate (1MEOX) (6TMS) MP


Replica Mass Spectra of Glucose-6-phosphate (1MEOX) (6TMS) MP

replicalib entry datedetectionmethodspecies
112 June 2003 MS-QuadM[2]Arabidopsis thaliana
412 May 2005  M[NIST] 
2705 June 2013  MRI_2013 
522 February 2005 MS-TOFM[STR] 
619 July 2007 MS-TOFVAR5Reference Substance
815 March 2005 MS-TOFM[6]Reference Substance
2430 March 2011  Fiehn_GC_2010 
901 October 2001 MS-TOFM[EIGTMS]Standard Addition
1001 January 2002 MS-TOFM[EIGTMS]Standard
2628 August 2012  MassBank GC 2010 Ara 
24 spectrum(a)
rotate: click+drag; translate: alt+click+drag; zoom: mousewheel; save: mol

Spectrum Details

analyteGlucose-6-phosphate (1MEOX) (6TMS) MP
analyte InChIInChI=1S/C25H64NO9PSi6/c1-28-26-20-22(30-37(2,3)4)24(32-39(8,9)10)25(33-40(11,12)13)23(31-38(5,6)7)21-29-36(27,34-41(14,15)16)35-42(17,18)19/h20,22-25H,21H2,1-19H3/b26-20+/t22-,23+,24+,25+/m0/s1
analyte mass722.26
citationSchauer N, Steinhauser D, Strelkov S, Schomburg D, Allison G, Moritz T, Lundgren K, Roessner-Tunali U, Forbes MG, Willmitzer L, Fernie AR, Kopka J (2005) FEBS Letters 579, 1332-1337
authorsKopka J, Max Planck Institute of Molecular Plant Physiology, Department of Molecular Plant Physiology (Prof. Willmitzer L), Am Muehlenberg 1, D-14476 Golm, Germany
lib entry date01 December 2003
metabolite roleMETB-METB
retention time (sec)2,081.7
retention index (VAR5 method, n-alkanes C10–C36)2,308.72 (predicted, according to Strehmel, N. et.al)
base peak (m/z)73
maximal intensity999
mass-intensity-peaks cardinality50 intensities
minimal m/z45
maximal m/z472
download JCAMP DXSpectrumJcampDx.ashx?id=fb4745db-8755-4ce7-a19c-0de1ebce343b
download MSPSpectrumMsp.ashx?id=fb4745db-8755-4ce7-a19c-0de1ebce343b


citationRoessner U, Wagner C, Kopka J, Trethewey RN, Willmitzer L (2000) Plant J 23, 131-142
deconvolutionAMDIS, National Institute of Standards and Technology, Gaithersburg, MD, USADIRECTION:Low to High; WIDTH: 20; SUBTRACTION: two; RESOLUTION: low; SENSITIVITY: low; SHAPE: low
derivatizationMEOX; TMSMethoxyamination:60min37°C; Trimethylsilylation:>45min37°C
detectorMS-Quadm/z = 35-600; scans:2/s; MD 800 Thermo-Finnigan, San Jose, CA, USA
extractionmethanol:water (4:1; v/v); 15min70°C 
ion sourceEI70eV
metabolic inactivationcut; liquid nitrogen; -80°C 
partitioningmethanol fraction of a methanol:water:chloroform (approx. 2:2:1, v/v/v) partitioning 
RIALKANEC12, C15, C19, C22, C28, C32, C36
separationGCCOLUMN:5%diphenyl-95%dimethylpolysiloxane (arylene), 30+10m, ID:0.25mm, DF:0.25microm, Rtx-5SilMS Integra-Guard, #NA (Restek, Bad Homburg, Germany); PROGRAM:iso1min70°C, ramp9°C/min, iso5min350°C; FLOW:Helium, 0.6ml/min; INJECTION:1microL, splitless, 230°C; TRANSFER:250°C; IONSOURCE:250°C

comments on this mass spectrum

Post a Comment
service last updated 31/08/2021 © 2008-2014 Golm Metabolome Database - All rights reserved